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诺奖得主MacMillan最新Nature:比Friedel-Crafts烷基化更强大的芳烃C-H烷基 ...
导读近日,诺贝尔化学奖得主、普林斯顿大学David W. C. MacMillan教授在Nature上报道了一种通用且高度模块化的反应,可用醇和羧酸作为烷基化剂直接烷基化天然芳烃C-H键。基于底层偶联机制的普遍性,动态轨道选择(dynamic ...
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