In the card setup you need to make sure support for bootable CD is turned on. If the card detects a media thats bootable, then it will boot from that instead of ID0.

I've been looking for a program to make a .img file off of some files on my HD and then make a bootable CD. I've tried Adaptec, Nero, and CDRWin. Adaptec only allows you to make an .img file from ...

How to Make an ISO Disk Image of a Microsoft Office Disk. An ISO disc image is a special file that stores the contents of an entire CD or DVD on your computer hard drive.